Steven Gerrard and Fernando Torres are both expected to feature tonight as Liverpool face Marseille in their opening Champions League group game.
After making a substitute appearance in Saturday's victory over Manchester United, Gerrard is likely to play a more significant role in France, with Torres also set for a return to the side following a hamstring injury.
The Spaniard is 9/2 with William Hill to open the scoring this evening, with Robbie Keane available at 6/1 as he continues to chase his first goal in Liverpool colours.
Ladbrokes makes Liverpool an 18/1 bet to be the highest scoring team in tonight's European fixtures, with Chelsea rated at 11/2 ahead of their home game against Bordeaux.
At 3/1, Werder Bremen are favourites in that particular market, as they start their campaign at home to Cypriot side Anorthosis Famagusta.
With eight games taking place around the continent, Paddy Power offers a money-back special in which all incorrect win-draw-win bets are refunded for the match in which the last goal of the night is scored.
Chelsea are favourites for the 2008-09 Champions League at 5/1 with SkyBet, which offers 14/1 on Liverpool tasting European glory once again.